156524-55-9

Upstream product

• 1777-03-3 2-triethylsilylacetylene 

Downstream Products

• 106583-99-7 carbonylchlorohydrido(3,5-dimethylpyrazole-N⁽²⁾)bis(triphenylphosphine)ruthenium(II) 
• 1415100-74-1 [ruthenium(II)(carbonyl)(chloride)(CHCHC₆H₄N(C₆H₄Me-4)2-4)] 
• 264189-21-1 [ruthenium(II)(carbonyl)(chloride)(CHCHC₆H₄OMe-4)] 
• 141216-63-9 [ruthenium(II)(carbonyl)(chloride)(CHCHC₆H₄Me-4)] 
• 1415100-78-5 [ruthenium(II)(carbonyl)(chloride)(CHCHC₆H₄CO₂Me-4)] 
• 1415100-80-9 [ruthenium(II)(carbonyl)(chloride)(CHCHC₆H₄NO₂-4)] 
• 1262014-02-7 [RuH(CO)(PPh₃)2(dimethylglyoxime(-1H))] 

Relevant academic research and scientific papers

A new catalytic route for the activation of sp-hybridized carbon-hydrogen bonds

(Chemical Equation Presented) Vinyl-substituted silicon compounds react selectively with terminal alkynes in the presence of complexes containing [Ru]-H and [Ru]-Si bonds to form functionalized silylethynes (see picture). This reaction opens up a new catalytic route for the preparation of a class of potent organosilicon reagents for organic synthesis.

New Ruthenium-Molybdenum and -Tungsten Heterodinuclear Complexes with trans-Styryl Ligand

New styryl ruthenium-molybdenum and -tungsten complexes Cp(CO)3M-Ru (trans-styryl)(CO)(PPh3)2 have been prepared by the metathetical reactions of Ru(trans-styryl)Cl(CO)(PPh3)2 with Na.The reactions of 2 with CO and with PMe3