156578-45-9Relevant academic research and scientific papers
Dramatic enhancement of reactivity of organosilicon compounds induced by complexation of bis(allyl)silanes with fluoride ion
Shibato, Atsushi,Itagaki, Yoshifumi,Tayama, Eiji,Hokke, Yasutoshi,Asao, Naoki,Maruoka, Keiji
, p. 5373 - 5382 (2007/10/03)
New type of fluoride ion catalyzed allylation agent (1a, 1b), allenylation agent (9, 10), and alkynylation agent (17) can be successfully utilized for various carbonyl substrates. The rate acceleration is ascribable to the shift of equilibrium to the chel
o-Bis(allyldimethylsilyl)benzene as a remarkably effective allylation agent for carbonyl compounds with Bu4NF catalyst
Asao, Naoki,Shibato, Atsushi,Itagaki, Yoshifumi,Jourdan, Fabrice,Maruoka, Keiji
, p. 3177 - 3180 (2007/10/03)
A new type of fluoride ion catalyzed allylation agent, o- bis(allyldimethylsilyl)benzene (1a) and bis(allyldimethylsilyl)methane (1b), can be successfully utilized for various carbonyl substrates. The rate acceleration is ascribable to the shift of equili
Phenylenbis(silandiyl triflates) - New Synthetic Building Blocks for Variously Structured Organosilicon Polymers
Uhlig, Wolfram
, p. 972 - 980 (2007/10/02)
Ortho-, meta-, and para-substituted phenylenbis(silandiyl triflates) are prepared as new useful building blocks for the synthesis of polymers with a regular alternating arrangement of an organosilicon unit and a ?-electron system (phenylene or ethynylene)
