156579-69-0

Basic information

• Product Name: {(η6-p-cymene)RuCl2(3-(4'-methylphenyl)pyrazole)}
• CAS NO: 156579-69-0
• Molecular Weight: 464.4
• Mol File: 156579-69-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {(η6-p-cymene)RuCl2(3-(4'-methylphenyl)pyrazole)}(CAS DataBase Reference)
• NIST Chemistry Reference: {(η6-p-cymene)RuCl2(3-(4'-methylphenyl)pyrazole)}(156579-69-0)
• EPA Substance Registry System: {(η6-p-cymene)RuCl2(3-(4'-methylphenyl)pyrazole)}(156579-69-0)

Safety Data

• Hazardous Substances Data: 156579-69-0(Hazardous Substances Data)

Upstream product

• 52462-29-0 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 
• 59843-75-3 3-p-tolyl-1H-pyrazole 

Relevant articles and documents

p-CYMENE RUTHENIUM(II) COMPLEXES WITH 3-SUBSTITUTED PYRAZOLE LIGANDS

The synthesis and characterisation of new mono- and dinuclear p-cymene-ruthenium(II) complexes (p-cymene = MeC6H4Pri-p) containing 3-substituted pyrazoles (LH) or pyrazolates (L) as ligands are reported .The new complexes belong to one of the following families (not all possible combinations): 6-p-cymene)RuCl2(LH)> (1-5),6-p-cymene)RuCl(LH)2>BF4 (6-11), 6-p-cymene)RuL(acac)> (acac = acetylacetonate) (12-15), 6-p-cymene)Ru(acac)(LH)>BF4 (16-19), 6-p-cymene)Ru(LH)3>2 (20-22), 6-p-cymene)RuL(LH)2>BF4 (23-25), 6-p-cymene)RuL2(LH)> (26-28), and the dinuclear 6-p-cymene)RuCl(μ-L)2M(CO)2> (M = Rh, Ir) (29-34).For the ruthenium-iridium complexes 6-p-cymene)RuCl(μ-ClPhpz)2Ir(CO)2> (33) and 6-p-cymene)RuCl(μ-MePhpz)2Ir(CO)2> (34) an equilibrium in solution is reached between two isomers that implies a reversible metal-metal bond formation accompanied by halide migration.