1565857-86-4

Basic information

• Product Name: 4,4,5,5-tetramethyl-2-(3-(thiophene-3-yl)phenyl)-1,3,2-dioxaborolane
• Synonyms: 4,4,5,5-tetramethyl-2-(3-(thiophene-3-yl)phenyl)-1,3,2-dioxaborolane
• CAS NO: 1565857-86-4
• Molecular Weight: 286.203
• Mol File: 1565857-86-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4,4,5,5-tetramethyl-2-(3-(thiophene-3-yl)phenyl)-1,3,2-dioxaborolane(CAS DataBase Reference)
• NIST Chemistry Reference: 4,4,5,5-tetramethyl-2-(3-(thiophene-3-yl)phenyl)-1,3,2-dioxaborolane(1565857-86-4)
• EPA Substance Registry System: 4,4,5,5-tetramethyl-2-(3-(thiophene-3-yl)phenyl)-1,3,2-dioxaborolane(1565857-86-4)

Safety Data

• Hazardous Substances Data: 1565857-86-4(Hazardous Substances Data)

Upstream product

• 99-09-2 3-nitro-aniline 
• 73183-34-3 bis(pinacol)diborane 
• 68716-48-3 4,4,5,5-tetramethyl-2-(3-nitrophenyl)-1,3,2-dioxaborolane 
• 872-31-1 3-Bromothiophene 
• 1565857-71-7 trimethyl(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)stannane 
• 210907-84-9 3-aminophenylboronic acid pinacolate 

Relevant articles and documents

Synthesis of trimethylstannyl arylboronate compounds by sandmeyer-type transformations and their applications in chemoselective cross-coupling reactions

A synthetic method based on Sandmeyer-type reactions to access both tin- and boron-substituted arenes from nitroaniline derivatives is described. This transformation can be applied to the synthesis of a series of functionalized trimethylstannyl arylboronates. In addition, the chemoselective reaction of the Stille and Suzuki-Miyaura cross-coupling reactions is explored, and a series of m- and p-terphenyl derivatives have been synthesized by conducting consecutive one-pot Stille and Suzuki-Miyaura cross-coupling reactions.