156593-34-9

Upstream product

• 1824-94-8 methyl beta-D-galactopyranoside 
• 156593-32-7 methyl 2-O-benzyl-6-bromo-3,4-O-cyclohexylidene-6-deoxy-β-D-galactopyranoside 
• 156593-31-6 methyl 6-bromo-3,4-O-cyclohexylidene-6-deoxy-β-D-galactopyranoside 
• 156593-39-4 methyl 3,4-O-cyclohexylidene-β-D-galactopyranoside 
• 200272-77-1 methyl 2-O-benzyl-6-chloro-3,4-O-cyclohexylidene-6-deoxy-β-D-galactopyranoside 
• 200272-72-6 methyl 6-chloro-3,4-O-cyclohexylidene-6-deoxy-β-D-galactopyranoside 
• 100-39-0 benzyl bromide 
• 933-40-4 cycloxexanone dimethyl ketal 
• 156593-33-8 methyl L-2-O-benzyl-3,4-O-cyclohexylidene-6-deoxy-β-arabino-hex-5-enopyranoside 

Downstream Products

• 161104-10-5 L-1-O-benzyl-5,6-O-cyclohexylidene-3-deoxy-chiro-inositol 
• 200272-99-7 (2R)-(2,3/4)-2,3-dihydroxy-4-benzyloxy-2,3-O-cyclohexylidenecyclohex-5-enone 
• 156712-77-5 D-4-O-benzyl-2,3-O-cyclohexylidene-6-deoxy-myo-1-inosose 
• 200274-39-1 4-O-benzyl-2,3-O-cyclohexylidene-6-deoxy-myo-inositol 
• 131435-06-8 1D-1,2,3,5/4-cyclohexanepentol 
• 40617-62-7 (-)-2-deoxy-allo-inositol 
• 200273-14-9 (1R,2R,4S,5R)-5-Benzyloxy-cyclohexane-1,2,4-triol 
• 200273-17-2 (1S,2R,4S,5S,6R)-5-Benzyloxy-6-fluoro-cyclohexane-1,2,4-triol 
• 200272-93-1 D-6-O-benzyl-3-O-benzoyl-1,2-O-cyclohexylidene-4-deoxy-neoinositol 
• 200273-10-5 L-2,4-di-O-benzoyl-1-O-benzyl-3-deoxy-chiro-inositol 
• 200272-97-5 D-5-O-acetyl-1-O-benzoyl-4-O-benzyl-2,3-O-cyclohexylidene-6-deoxy-myo-inositol 
• 200272-87-3 L-1-O-benzyl-5,6-O-cyclohexylidene-3-deoxy-2,4-di-O-mesyl-chiro-inositol 
• 200272-91-9 D-3-O-benzoyl-6-O-benzyl-1,2-O-cyclohexylidene-4-deoxy-5-O-mesyl-neo-inositol 
• 200273-15-0 L-2,4-di-O-benzoyl-1-O-benzyl-3-deoxy-5-O-pivaloyl-chiro-inositol 

Relevant academic research and scientific papers

Stereoselective synthesis of 6-deoxy and 3,6-dideoxy-D-myo-inositol precursors of deoxy-myo-inositol phosphate analogues from D-galactose

The synthesis of chiral protected D-6-deoxy-myo-inositol derivatives from D-galactose is described. Ferrier rearrangement of hexenogalactopyranosides has been employed to produce the corresponding 6- deoxy-cyclohexanone polyols. The stereoselectivity of the carbocyclic transformation was discussed on the basis of the experimental data and a mechanism has been proposed. From deoxy-inososes, the access to a variety of 6-deoxy and 3,6-dideoxy-myo-inositol was performed to prepare suitable monool, diol and triol precursors for the synthesis of D-deoxy-myo-inositol phosphate analogues.