156643-24-2

Basic information

• Product Name: N-Isopropyl-2-broMoaniline
• Synonyms: N-Isopropyl-2-broMoaniline
• CAS NO: 156643-24-2
• Molecular Formula: C9H12BrN
• Molecular Weight: 214.10228
• Mol File: 156643-24-2.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 266.0±23.0 °C(Predicted)
• Appearance: /
• Density: 1.351±0.06 g/cm3(Predicted)
• PKA: 4.04±0.20(Predicted)
• CAS DataBase Reference: N-Isopropyl-2-broMoaniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-Isopropyl-2-broMoaniline(156643-24-2)
• EPA Substance Registry System: N-Isopropyl-2-broMoaniline(156643-24-2)

Safety Data

• Hazardous Substances Data: 156643-24-2(Hazardous Substances Data)

Upstream product

• 598-53-8 isopropyl methyl ether 
• 615-36-1 2-bromoaniline 
• 1194487-51-8 C₉H₁₀BrN 
• 67-64-1 acetone 
• 75-30-9 2-iodo-propane 
• 4001-73-4 2-Bromobenzamide 

Downstream Products

• 1023030-66-1 methyl (2-bromophenyl)propan-2-ylcarbamate 

Relevant articles and documents

Bivalent platinum coordination compound and application thereof as well as organic photoelectric device

The invention belongs to the technical field of organic electroluminescent materials and provides a bivalent platinum coordination compound and the application thereof as well as an organic photoelectric device. The bivalent platinum coordination compound provided by the invention has a chemical structure as shown in a formula I and is a blue light emitting material. The blue light emitting material serves as a doping material in OLED light-emitting devices and equipment, and the peak value of blue light emitted by the blue light emitting material ranges between 450 and 470 nm. Benzimidazole carbene is introduced into a ligand structure of the bivalent platinum coordination compound; the benzimidazole carbene structure has proper triplet energy, has a more stable carbon platinum coordination bond compared with a nitrogen platinum coordination bond, and has a more stable excited state conjugated system compared with the imidazole carbene structure. Therefore, the whole blue light spectrum is narrower, molecules are more stable in photoluminescence and device electroluminescence, the development of the blue light emitting material is promoted and the properties of light-emitting devices are improved.

Thermal switchability of N-chelating hoveyda-type catalyst containing a secondary amine ligand

An investigation of aza analogues of the popular Hoveyda-Grubbs catalyst containing a secondary amine ligand is presented, proving the crucial impact of steric as well as electronic factors on the catalyst's stability and performance. The issue of latency in the reactivity profile of studied catalysts is examined, followed by structural and application studies.

Enantioselective synthesis of 2-methyl indolines by palladium catalysed asymmetric C(sp3)-H activation/cyclisation

The first example of the enantioselective methyl C-H activation by an intramolecular ArPdX species and subsequent cyclisation was developed. Palladium catalysts using commercially available chiral diphosphines yield good ee's (up to 93% ee) in the synthesis of 2-methyl indolines from 2-halo N-isopropyl anilides. This approach was also employed for the synthesis of enantioenriched cyclohexyl fused indolines with moderate enantioselectivities.