1566557-16-1

Basic information

• Product Name: (R,E)-P,P-diphenyl-N-(1-phenyl-4-(trimethylsilyl)hexa-1,4,5-trien-3-yl)phosphinic amide
• Synonyms: (R,E)-P,P-diphenyl-N-(1-phenyl-4-(trimethylsilyl)hexa-1,4,5-trien-3-yl)phosphinic amide
• CAS NO: 1566557-16-1
• Molecular Weight: 443.601
• Mol File: 1566557-16-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R,E)-P,P-diphenyl-N-(1-phenyl-4-(trimethylsilyl)hexa-1,4,5-trien-3-yl)phosphinic amide(CAS DataBase Reference)
• NIST Chemistry Reference: (R,E)-P,P-diphenyl-N-(1-phenyl-4-(trimethylsilyl)hexa-1,4,5-trien-3-yl)phosphinic amide(1566557-16-1)
• EPA Substance Registry System: (R,E)-P,P-diphenyl-N-(1-phenyl-4-(trimethylsilyl)hexa-1,4,5-trien-3-yl)phosphinic amide(1566557-16-1)

Safety Data

• Hazardous Substances Data: 1566557-16-1(Hazardous Substances Data)

Upstream product

• 6224-91-5 trimethyl(prop-1-ynyl)silane 
• 528838-87-1 C₂₁H₁₈NOP 
• 129217-85-2 trimethyl (3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)prop-1-yn-1-yl)silane 

Relevant articles and documents

NHC-Cu-catalyzed addition of propargylboron reagents to phosphinoylimines. Enantioselective synthesis of trimethylsilyl-substituted homoallenylamides and application to the synthesis of S-(-)-cyclooroidin

A catalytic method for the efficient and enantioselective addition of a 1-trimethylsilyl-substituted allene moiety to phosphinoylimines is presented. Transformations are promoted by 5.0 mol % of a copper complex of an N-heterocyclic carbene in the presenc