1567373-99-2

Basic information

• Product Name: 1,3-dimethyl 2-(5-oxo-5-phenylpentyl)malonate
• Synonyms: 1,3-dimethyl 2-(5-oxo-5-phenylpentyl)malonate
• CAS NO: 1567373-99-2
• Molecular Weight: 292.332
• Mol File: 1567373-99-2.mol

Chemical Properties

• CAS DataBase Reference: 1,3-dimethyl 2-(5-oxo-5-phenylpentyl)malonate(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-dimethyl 2-(5-oxo-5-phenylpentyl)malonate(1567373-99-2)
• EPA Substance Registry System: 1,3-dimethyl 2-(5-oxo-5-phenylpentyl)malonate(1567373-99-2)

Safety Data

• Hazardous Substances Data: 1567373-99-2(Hazardous Substances Data)

Upstream product

• 108-59-8 malonic acid dimethyl ester 
• 71-43-2 benzene 
• 4509-90-4 5-bromovaleroyl chloride 
• 4509-91-5 5-bromo-1-phenyl-1-pentanone 

Relevant articles and documents

The copper-catalyzed selective monoalkylation of active methylene compounds with alkylsilyl peroxides

A novel method for a mild copper-catalyzed selective monoalkylation of active methylene compounds with various alkylsilyl peroxides has been developed. The reaction has a broad substrate scope and our mechanistic studies suggest the participation of radical species in this alkylation reaction.

Anodic cyclization of dimethyl 2-(5-aryl-5-oxopentyl)malonates into the corresponding dimethyl 2-aroylcyclopentane-1,1-dicarboxylates

A wide range of dimethyl 2-(5-aryl-5-oxopentyl)malonates was electrooxidized in methanol, in the presence of catalytic amount of potassium iodide, to give the corresponding dimethyl 2-aroylcyclopentane-1,1- dicarboxylates in high yields. The reactions were carried out under extremely mild reaction conditions, in which the optimal amount of electrolytic current ranged from 2.24 to 2.35 Fmol-1. The reaction presumably proceeded via a two-electron oxidation process, in which iodide ions played an important role as the electron carrier between the anode and the substrate.