156767-62-3

Basic information

• Product Name: (R,E)-1-methyl-4-(prop-1-en-1-ylsulfinyl)benzene
• Synonyms: (R,E)-1-methyl-4-(prop-1-en-1-ylsulfinyl)benzene
• CAS NO: 156767-62-3
• Molecular Weight: 180.271
• Mol File: 156767-62-3.mol

Chemical Properties

• CAS DataBase Reference: (R,E)-1-methyl-4-(prop-1-en-1-ylsulfinyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (R,E)-1-methyl-4-(prop-1-en-1-ylsulfinyl)benzene(156767-62-3)
• EPA Substance Registry System: (R,E)-1-methyl-4-(prop-1-en-1-ylsulfinyl)benzene(156767-62-3)

Safety Data

• Hazardous Substances Data: 156767-62-3(Hazardous Substances Data)

Upstream product

• 75-07-0 acetaldehyde 
• 1730-25-2 (E)-1-propenylmagnesium bromide 
• 190448-84-1 (1S,5R,7R)-10,10-Dimethyl-4-((R)-toluene-4-sulfinyl)-3-thia-4-aza-tricyclo[5.2.1.0^1,5]decane 3,3-dioxide 
• 10439-23-3 4-methylbenzenesulfinyl chloride 

Downstream Products

• 156662-80-5 (3R,4R)-2,2-dichloro-4-ethyl-3-methyl-4-p-tolylthio-γ-butyrolactone 
• 156662-81-6 (3S,4R)-4-ethyl-3-methyl-4-p-tolylthio-γ-butyrolactone 
• 172376-24-8 Methanesulfonic acid (E)-(R)-1-[(S)-1-((1aR,3aR,3bS,5aS,6R,8aS,8bS,10R,10aR)-10-methoxy-3a,5a-dimethyl-hexadecahydro-cyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-6-yl)-ethyl]-2-((S)-toluene-4-sulfinyl)-but-2-enyl ester 
• 172376-21-5 (-)-(22Z,24S,R_S)-6β-methoxy-24-methyl-23-(p-tolylsulfinyl)-3α,5-cyclo-5α-ergost-22-ene 
• 172491-38-2 (-)-(22Z,24R,R_S)-6β-methoxy-24-methyl-23-(p-tolylsulfinyl)-3α,5-cyclo-5α-ergost-22-ene 
• 186132-56-9 Methanesulfonic acid (E)-(S)-1-ethyl-2-((S)-toluene-4-sulfinyl)-but-2-enyl ester 
• 186132-55-8 Methanesulfonic acid (E)-(R)-1-ethyl-2-((S)-toluene-4-sulfinyl)-but-2-enyl ester 
• 131974-05-5 (E)-5(S)-methyl-4(R_S)-(p-tolylsulfinyl)non-3-ene 
• 131974-04-4 (Z)-5(S)-methyl-4(R_S)-(p-tolylsulfinyl)non-3-ene 
• 131974-03-3 (E)-5(R)-methyl-4(R_S)-(p-tolylsulfinyl)non-3-ene 
• 131974-06-6 (Z)-5(R)-methyl-4(R_S)-(p-tolylsulfinyl)non-3-ene 
• 172376-23-7 (+)-(22S,23E,R_S)-22-hydroxy-6β-methoxy-23-(p-tolylsulfinyl)-3α,5-cyclo-5α-26,27-dinorcholest-23-ene 
• 172376-22-6 (+)-(22R,23E,R_S)-22-hydroxy-6β-methoxy-23-(p-tolylsulfinyl)-3α,5-cyclo-5α-26,27-dinorcholest-23-ene 
• 186132-53-6 (E)-(R)-4-((S)-Toluene-4-sulfinyl)-hex-4-en-3-ol 

Relevant articles and documents

Asymmetric synthesis of chiral sulfoxides and sulfinimines by using N-sulfinylsultam

Bornane-10,2-sultam 1 is stereoselectively converted by DMAP-assisted sulfinylation to diastereomerically pure (2R)-N-[(R)-p-tolylsulfinyl]-bornane-10,2-sultam 2 in 77% yield. The crystalline sulfinylating agent 2 reacts with a variety of nucleophiles to afford sulfoxides 3 and sulfinimines 5 in excellent yields and enantioselectivities.

A Formal and Enantioselective Synthesis of (-)-Serricornin, the Sex Pheromone of the Cigarette Beetle (Lasioderma serricorne F.)

A synthesis of (-)-Serricornin is described.The (4S,5S)-4-methyl-5-ethyl δ-valerolactone 8 has been synthesized with a high degree of enantioselectivity starting from (R)-(+)-(E)-1-propenyl p-tolylsulfoxide 2, having the enantioselective Marino's lactoniz