190448-84-1

Upstream product

• 10439-23-3 4-methylbenzenesulfinyl chloride 
• 94594-90-8 (2R)-bornane-10,2-sultam 

Downstream Products

• 188447-82-7 (S)-(+)-N-(crotonylidene)-p-toluenesulfinamide 
• 190448-86-3 4-Methyl-benzenesulfinic acid (S)-pent-(E)-ylideneamide 
• 58059-08-8 tert-butyl (R)-p-toluenesulfinylacetate 
• 1519-39-7 (R)-methyl p-tolyl sulfoxide 
• 54828-68-1 (R)-p-tolyl vinyl sulfoxide 
• 89708-79-2 (R)-(+)-allyl p-tolyl sulphoxide 
• 1517-74-4 (+)-(R)-isopropyl p-tolyl sulfoxide 
• 99930-80-0 1-pentynyl p-tolyl (+)-(S)-sulfoxide 
• 4820-08-0 (R)-1-(benzylsulfinyl)-4-methylbenzene 
• 143810-77-9 (S_S)-2-(p-tolylsulfinyl)thiophene 
• 350479-90-2 (S,E)-N-benzylidene-4-methylbenzenesulfinamide 
• 33418-16-5 (-)-(R,Z)-1-(p-methylphenylsulfinyl)prop-1-ene 
• 158009-36-0 (S)-(+)-N-(isopropylmethylidene)-p-toluenesulfinamide 
• 190448-87-4 (S,E)-N-(cyclohexylmethylene)-4-methylbenzenesulfinamide 

Relevant academic research and scientific papers

Asymmetric synthesis of chiral sulfoxides and sulfinimines by using N-sulfinylsultam

Bornane-10,2-sultam 1 is stereoselectively converted by DMAP-assisted sulfinylation to diastereomerically pure (2R)-N-[(R)-p-tolylsulfinyl]-bornane-10,2-sultam 2 in 77% yield. The crystalline sulfinylating agent 2 reacts with a variety of nucleophiles to afford sulfoxides 3 and sulfinimines 5 in excellent yields and enantioselectivities.