1569093-79-3Relevant articles and documents
Planar chiral tetrasubstituted [2.2]paracyclophane: Optical resolution and functionalization
Morisaki, Yasuhiro,Gon, Masayuki,Sasamori, Takahiro,Tokitoh, Norihiro,Chujo, Yoshiki
, p. 3350 - 3353 (2014)
We achieved optical resolution of 4,7,12,15-tetrasubstituted [2.2]paracyclophane and subsequent transformation to planar chiral building blocks. An optically active propeller-shaped macrocyclic compound containing a planar chiral cyclophane core was synthesized, showing excellent chiroptical properties such as high fluorescence quantum efficiency and a large circularly polarized luminescence dissymmetry factor.