Journal of the American Chemical Society p. 3350 - 3353 (2014)
Update date:2022-08-05
Topics:
Morisaki, Yasuhiro
Gon, Masayuki
Sasamori, Takahiro
Tokitoh, Norihiro
Chujo, Yoshiki
We achieved optical resolution of 4,7,12,15-tetrasubstituted [2.2]paracyclophane and subsequent transformation to planar chiral building blocks. An optically active propeller-shaped macrocyclic compound containing a planar chiral cyclophane core was synthesized, showing excellent chiroptical properties such as high fluorescence quantum efficiency and a large circularly polarized luminescence dissymmetry factor.
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Doi:10.1016/j.tetlet.2014.01.066
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