1569097-39-7Relevant academic research and scientific papers
Glycosylation Reactions Using Phenyl(trifluoroethyl)iodonium Salts
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Paragraph 0127; 0128, (2015/04/15)
Provided are methods for the preparation of glycosylation products, including those represented by formula I: [in-line-formulae]Sugar-O—R′??I[/in-line-formulae]comprising the step of combining R′—OH, a glycosyl sulfide glycosyl donor (“thioglycoside donor
An Air- and water-stable iodonium salt promoter for facile thioglycoside activation
Chu, An-Hsiang Adam,Minciunescu, Andrei,Montanari, Vittorio,Kumar, Krishna,Bennett, Clay S.
supporting information, p. 1780 - 1782 (2014/04/17)
The air- and water-stable iodonium salt phenyl(trifluoroethyl)iodonium triflimide is shown to activate thioglycosides for glycosylation at room temperature. Both armed and disarmed thioglycosides rapidly undergo glycosylation in 68-97% yield. The reaction
