1569304-16-0

Basic information

• Product Name: (ZnI₂(methanol))₃(N,N′,N″-tris(2-pyridinylethyl)-1,3,5-benzenetricarboxamide)
• CAS NO: 1569304-16-0
• Molecular Weight: 1576.33
• Mol File: 1569304-16-0.mol

Chemical Properties

• CAS DataBase Reference: (ZnI₂(methanol))₃(N,N′,N″-tris(2-pyridinylethyl)-1,3,5-benzenetricarboxamide)(CAS DataBase Reference)
• NIST Chemistry Reference: (ZnI₂(methanol))₃(N,N′,N″-tris(2-pyridinylethyl)-1,3,5-benzenetricarboxamide)(1569304-16-0)
• EPA Substance Registry System: (ZnI₂(methanol))₃(N,N′,N″-tris(2-pyridinylethyl)-1,3,5-benzenetricarboxamide)(1569304-16-0)

Safety Data

• Hazardous Substances Data: 1569304-16-0(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 1446319-44-3 N,N’,N’’-tris(2-pyridinylethyl)-1,3,5-benzenetricarboxamide 
• 10139-47-6 zinc(II) iodide 

Relevant articles and documents

Halogen effects on photoluminescence and catalytic properties: A series of spatially arranged trimetallic zinc(ii) complexes

Self-assembly of ZnX2 (X = Cl, Br, and I) with N,N′,N′′-tris(2-pyridinylethyl)-1,3,5-benzenetricarboxamide (L) as a tridentate N-donor ligand yields discrete C3-symmetric trimetallic zinc(ii) complexes, [Zn3X6L(MeOH) 3]. These form, via π...π interactions and NH...OC hydrogen-bonds, an ensemble constituting a unique columnar stacking structure in an abab... staggered fashion. For this series of complexes, the halogen effects on the photoluminescence, catalysis, and thermal properties were investigated. For [Zn3Cl6L(MeOH)3], a blue luminescence was observed at 462 nm (λex = 369 nm). The transesterification catalysis showed significant halogen effects in the order [Zn3I6L(MeOH)3] > [Zn3Cl 6L(MeOH)3] > [Zn3Br6L(MeOH) 3] in methanol, whereas in a mixture of methanol and acetonitrile, the order was [Zn3I6L(MeOH)3] > [Zn 3Br6L(MeOH)3] > [Zn3Cl 6L(MeOH)3]. Such notable different effects among the three complexes might be explained by the halogens' electronic effects and dissociation properties.