156942-22-2

Basic information

• Product Name: Ethanone, 1-[4-(1,3,2-dioxaborinan-2-yl)phenyl]-
• CAS NO: 156942-22-2
• Molecular Formula: C11H13BO3
• Molecular Weight: 204.033
• Mol File: 156942-22-2.mol

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-[4-(1,3,2-dioxaborinan-2-yl)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-[4-(1,3,2-dioxaborinan-2-yl)phenyl]-(156942-22-2)
• EPA Substance Registry System: Ethanone, 1-[4-(1,3,2-dioxaborinan-2-yl)phenyl]-(156942-22-2)

Safety Data

• Hazardous Substances Data: 156942-22-2(Hazardous Substances Data)

Upstream product

• 99-90-1 para-bromoacetophenone 
• 504-63-2 trimethyleneglycol 
• 1630-79-1 tetrakis(dimethylamido)diborane 
• 13826-25-0 [2,2']bi[[1,3,2]dioxaborinanyl] 
• 149104-90-5 4-acetylphenylboronic acid 

Downstream Products

• 235416-34-9 1-(4-(piperidine-1-carbonyl)phenyl)ethanone 
• 1416556-11-0 3-phenyl-N-{phenyl[4-(trifluoromethyl)phenyl]methyl}-pyridin-2-amine 
• 94705-09-6 (4-acetylphenyl)(phenyl)methanol 

Relevant articles and documents

PROCESS FOR THE BORYLATION OF ORGANOHALIDES

The present invention relates to a process for the borylation of organohalides.

Borylation of organo halides and triflates using tetrakis(dimethylamino) diboron

We report a new in situ borylation method using tetrakis(dimethylamino) diboron, DMA4B2, in the presence of a diol. Our method uses standard borylation conditions and readily available Pd-catalysts. The scope of this method includes aryl halides and triflates as well as vinyl halides and triflates. The method successfully works with a broad range of diols, enabling the selection of the best boronic ester for subsequent Suzuki coupling.

Alkynes as activators in the nickel-catalysed addition of organoboronates to aldehydes

Alkynes act not as substrates but as co-catalysts in the presence of a nickel catalyst, an organoboronate and an aldehyde to promote the addition reaction between the substrates in combination with H2O. The Royal Society of Chemistry 2005.