156995-24-3Relevant academic research and scientific papers
Preparation and x-ray structure of [2,4-di-t-butyl-6-(N,N-dimethylaminomethyl) phenyl]dithioxophosphorane stabilized by intramolecular coordination
Yoshifuji, Masaaki,Kamijo, Kazunori,Toyota, Kozo
, p. 3971 - 3974 (1994)
[2,4-Di-t-butyl-6-(N,N-dimethylaminomethyl)phenyl]dithioxophosphorane was prepared by the reaction of the corresponding phosphine and elemental sulfur. The structure of the dithioxophosphorane was analyzed by X-ray crystallography, which indicated a stron
Preparation and properties of stabilized thioxophosphine sulfides bearing the 4-t-butyl-2,6-bis(dialkylaminomethyl)phenyl or the 2,4-di-t- butyl-6-(dialkylaminomethyl)phenyl substituents
Kamijo, Kazunori,Otoguro, Akihiko,Toyota, Kozo,Yoshifuji, Masaaki
, p. 1335 - 1342 (2007/10/03)
Stabilized thioxophosphine sulfides bearing the 4-t-butyl-2,6- bis(dialkylaminomethyl)phenyl or the 2,4-di-t-butyl- 6(dialkylaminomethyl)phenyl group, as well as their 15N labeled analogs, were prepared. Intramolecular interaction between the n
2,4-Di-tert-butyl-6-piperidinophenyl as a Sterically and Electronically Stabilizing Group and X-Ray Analysis of the Corresponding Diselenoxophosphorane
Yoshifuji, Masaaki,Sangu, Shinya,Kamijo, Kazunori,Toyota, Kozo
, p. 297 - 298 (2007/10/02)
The 2,4-di-tert-butyl-6-(1-piperidino)phenyl group is utilized to stabilize diselenoxophosphorane and the structure determined by X-ray analysis indicates coordination of the nitrogen lone-pair to the P-atom to form a four-membered ring with a remarkably
