Preparation and x-ray structure of [2,4-di-t-butyl-6-(N,N-dimethylaminomethyl) phenyl]dithioxophosphorane stabilized by intramolecular coordination

Article abstract of DOI:10.1016/S0040-4039(00)76716-5

[2,4-Di-t-butyl-6-(N,N-dimethylaminomethyl)phenyl]dithioxophosphorane was prepared by the reaction of the corresponding phosphine and elemental sulfur. The structure of the dithioxophosphorane was analyzed by X-ray crystallography, which indicated a stron