1570-60-1

Upstream product

• 98-87-3 benzylidene dichloride 
• 134-32-7 1-amino-naphthalene 
• 90-15-3 α-naphthol 
• 100-52-7 benzaldehyde 
• 529-34-0 3,4-dihydronaphthalene-1(2H)-one 
• 57366-68-4 5,6,8,9-tetrahydro-7-phenyldibenzolacridine 
• 6327-84-0 diethyl trans-2-benzoyl-3-phenylcyclopropane-1,1-dicarboxylate 
• 6327-84-0 diethyl cis-2-benzoyl-3-phenylcyclopropane-1,1-dicarboxylate 
• 6261-32-1 2-benzylidene-1-tetralone 

Relevant academic research and scientific papers

Scandium(III) Triflate-Catalyzed Reaction of Aroyl-Substituted Donor-Acceptor Cyclopropanes with 1-Naphthylamines: Access to Dibenzo[ c, h]acridines

The reaction of aroyl-substituted donor-acceptor (D-A) cyclopropanes with two equivalents of 1-naphthylamines in the presence of a catalytic amount of scandium(III) triflate provides access to dibenzo[c,h]acridines. The key steps of the transformation are the formation of nucleophilic ring-opening products from the D-A cyclopropanes and 1-naphthylamines and their subsequent fragmentation and cyclization. The method has a reasonable substrate scope, and the products are formed in 50-70% yields.

Cyclometalated pt complexes of cnc pincer ligands: Luminescence and cytotoxic evaluation

In the framework of our attempts to develop cyclometalated Pt(II) complexes toward bifunctional targeting inhibitors or agents for photodynamic therapy, diagnostics, and bioimaging, a series of bis-cyclometalated Pt(II) complexes [Pt(CNC)(L)] (L = DMSO, MeCN) containing various (CNC)2- ligands based on 2,6-diphenylpyridine were synthesized and characterized analytically and spectroscopically, focusing on their electrochemical, luminescence, and antiproliferative properties. Electrochemical experiments and UV-vis absorption spectroscopy suggest ligand-centered LUMOs and metal-centered HOMOs in line with DFT calculations. Extension of the ancillary phenyl to naphthyl cores and a central 4-phenylpyridine group instead of pyridine results in bathochromic shifts of the long-wavelength absorption bands ranging from 420 to 440 nm, with the latter shift being more pronounced. The complexes of the fused CNC heterocyclic systems dba (H2dba = dibenzo[c,h]acridine), db(ph)a (H2db(ph)a = 7-phenyldibenzo[c,h]acridine), and bzqph (HbzqphH = 2-phenylbenzo[h]quinoline) absorb far more red-shifted in the range 500-530 nm. All complexes show reversible first electrochemical reductions and irreversible oxidations with an electrochemical gap of about 3 V, roughly in line with the absorption energies. While the 2,6-diphenylpyridine complexes [Pt(CNC)(DMSO)] show no luminescence at ambient temperature in solution, the fused dba, db(ph)a, and bzqph derivatives are efficient triplet emitters at ambient temperature with emission wavelengths in the region 575-600 nm and quantum yields ranging from 7 to 23%. Vibrationally resolved emission spectra calculated in the framework of DFT faithfully reproduce the experimental data. TD-DFT calculations at the excited-state T1 geometry reveal intraligand π-π*/MLCT character of the emission for all three investigated complexes. Antiproliferative tests on selected complexes gave very different toxicities, ranging from lower than 1 μM to virtually nontoxic. The data allowed drawing some structure-activity relationships (SAR), even though variations in solubility could also significantly account for the different toxicities.

ELECTRONIC DEVICE COMPRISING ORGANIC SEMICONDUCTING MATERIAL

PROBLEM TO BE SOLVED: To provide a compound capable of being used for an organic semiconducting material, and an electronic device comprising at least one of the compound. SOLUTION: There is provided the compound represented by formula (I), where R1-