157024-67-4

Basic information

• Product Name: β-Glucosylglycerol 2,3,4,6-Tetraacetate
• Synonyms: β-Glucosylglycerol 2,3,4,6-Tetraacetate;2-(Tetraacetylglucosido)glycerol;2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosyl Glycerol;2-Hydroxy-1-(hydroxyMethyl)ethyl β-D-Glucopyranoside 2,3,4,6-Tetraacetate
• CAS NO: 157024-67-4
• Molecular Formula: C₁₇H₂₆O₁₂
• Molecular Weight: 422.38114
• Product Categories: Carbohydrates & Derivatives;Intermediates;Carbohydrates & Derivatives, Intermediates
• Mol File: 157024-67-4.mol
• Article Data: 2

Chemical Properties

• Melting Point: 103 °C
• Boiling Point: 527.2±50.0 °C(Predicted)
• Appearance: /
• Density: 1.35±0.1 g/cm3(Predicted)
• Solubility: Chloroform, Dichloromethane, Ethanol, Ethyl Acetate, Methanol,
• PKA: 13.83±0.10(Predicted)
• CAS DataBase Reference: β-Glucosylglycerol 2,3,4,6-Tetraacetate(CAS DataBase Reference)
• NIST Chemistry Reference: β-Glucosylglycerol 2,3,4,6-Tetraacetate(157024-67-4)
• EPA Substance Registry System: β-Glucosylglycerol 2,3,4,6-Tetraacetate(157024-67-4)

Safety Data

• Hazardous Substances Data: 157024-67-4(Hazardous Substances Data)

Usage

Chemical Properties

White Solid

Uses

Protected β-Glucosylglycerol, and an intermediate in its synthesis.

Upstream product

• 157024-66-3 1,3-di-O-benzyl-2-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-sn-glycerol 
• 76222-76-9 (ξ-2-phenyl-[1,3]dioxan-5-yl)-[tetra-O-acetyl-β-D-glucopyranoside 
• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 
• 604-69-3 β-D-glucose pentaacetate 

Downstream Products

• 534-68-9 2-O-β-D-glucosyl-glycerol 

Relevant articles and documents

Synthesis of glycosyl glycerols and related glycolipids

Several isomeric glycosyl glycerols were synthesized. Acetylated allyl glycosides of D-glucose and D-galactose were transformed into 1-O-(glycopyranosyl)-rac-glycerols in a three step procedure via the corresponding 2,3-epoxypropyl glycosides and the peracetylated glycosyl glycerols. Tetra-O-benzyl-D-glucose was glycosylated with 1,3-di-O-benzylglycerol to give the α-anomer preferentially. The 2-O-(tetra-O-acetyl-β-glycopyranosyl)-sn-glycerols and 2-O-(β-glycopyranosyl)-sn-glycerols of D-glucose, D-galactose and N-acetyl-D-glucosamine and the corresponding α-derivatives of D-mannose were synthesized by selective glycosylation methods from 1,3-di-O-benzylglycerol and 1,3-O-benzylideneglycerol, respectively, and activated sugar compounds followed by hydrogenolysis. After long chain acylation and selective deacetylation the 1,3-di-O-acyl-2-O-β-glycopyranosyl)-sn-glycerols of D-glucose, D-galactose and N-acetyl-D-glucosamine and the corresponding α-derivative of D-mannose were synthesized.