157024-66-3

Upstream product

• 6972-79-8 dibenzyl glycerol 
• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 
• 604-69-3 β-D-glucose pentaacetate 

Downstream Products

• 157024-67-4 (β,β'-dihydroxy-isopropyl)-(tetra-O-acetyl-β-D-glucopyranoside) 
• 250608-15-2 1,3-di-O-benzyl-2-O-(β-D-glucopyranosyl)-sn-glycerol 
• 250608-16-3 1,3-di-O-benzyl-2-O-(6-O-butanoyl-β-D-glucopyranosyl)-sn-glycerol 
• 250608-21-0 1,3-di-O-benzyl-2-O-(6-O-octanoyl-β-D-glucopyranosyl)-sn-glycerol 
• 250608-22-1 1,3-di-O-benzyl-2-O-(6-O-decanoyl-β-D-glucopyranosyl)-sn-glycerol 
• 250608-17-4 1,3-di-O-benzyl-2-O-(2,3,4,6-tetra-O-chloroacetyl-β-D-glucopyranosyl)-sn-glycerol 
• 534-68-9 2-O-β-D-glucosyl-glycerol 

Relevant academic research and scientific papers

Synthesis of glycosyl glycerols and related glycolipids

Several isomeric glycosyl glycerols were synthesized. Acetylated allyl glycosides of D-glucose and D-galactose were transformed into 1-O-(glycopyranosyl)-rac-glycerols in a three step procedure via the corresponding 2,3-epoxypropyl glycosides and the peracetylated glycosyl glycerols. Tetra-O-benzyl-D-glucose was glycosylated with 1,3-di-O-benzylglycerol to give the α-anomer preferentially. The 2-O-(tetra-O-acetyl-β-glycopyranosyl)-sn-glycerols and 2-O-(β-glycopyranosyl)-sn-glycerols of D-glucose, D-galactose and N-acetyl-D-glucosamine and the corresponding α-derivatives of D-mannose were synthesized by selective glycosylation methods from 1,3-di-O-benzylglycerol and 1,3-O-benzylideneglycerol, respectively, and activated sugar compounds followed by hydrogenolysis. After long chain acylation and selective deacetylation the 1,3-di-O-acyl-2-O-β-glycopyranosyl)-sn-glycerols of D-glucose, D-galactose and N-acetyl-D-glucosamine and the corresponding α-derivative of D-mannose were synthesized.