157035-13-7

Basic information

• Product Name: (E)-1-(3-(benzyloxy)prop-1-en-1-yl)-4-bromobenzene
• Synonyms: (E)-1-(3-(benzyloxy)prop-1-en-1-yl)-4-bromobenzene
• CAS NO: 157035-13-7
• Molecular Weight: 303.198
• Mol File: 157035-13-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (E)-1-(3-(benzyloxy)prop-1-en-1-yl)-4-bromobenzene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-(3-(benzyloxy)prop-1-en-1-yl)-4-bromobenzene(157035-13-7)
• EPA Substance Registry System: (E)-1-(3-(benzyloxy)prop-1-en-1-yl)-4-bromobenzene(157035-13-7)

Safety Data

• Hazardous Substances Data: 157035-13-7(Hazardous Substances Data)

Upstream product

• 1122-91-4 4-bromo-benzaldehyde 
• 24393-53-1 ethyl (E)-3-(4-bromophenyl)-2-propenoate 
• 105515-33-1 (2E)-3-(4-bromophenyl)prop-2-en-1-ol 
• 100-39-0 benzyl bromide 

Downstream Products

• 202645-40-7 O-benzyl-3-(4-bromophenyl)-2,3-epoxypropanol 
• 157035-17-1 3-(3-{4-[3-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-propyl]-phenoxy}-4-methoxy-phenyl)-propionic acid ethyl ester 
• 157035-18-2 3-(3-{4-[3-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-propyl]-phenoxy}-4-methoxy-phenyl)-propionic acid 
• 157035-19-3 3-(3-{4-[2-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-propyl]-phenoxy}-4-methoxy-phenyl)-propionic acid 
• 157035-16-0 [1-Benzyloxymethyl-2-(4-bromo-phenyl)-ethoxy]-tert-butyl-dimethyl-silane 
• 157035-15-9 O-benzyl-3-(4-bromophenyl)-2-hydroxypropanol 
• 126191-23-9 combretastatin D-2 

Relevant articles and documents

Diastereoselective borocyclopropanation of allylic ethers using a boromethylzinc carbenoid

A borocyclopropanation of (E)- and (Z)-allylic ethers and styrene derivatives via the Simmons-Smith reaction using a novel boromethylzinc carbenoid is described. The carbenoid precursor is prepared via a 3-step sequence from inexpensive and commercially available starting materials. This methodology allows for the preparation of 1,2,3-substituted borocyclopropanes in high yields and diastereoselectivities. Several postfunction-alization reactions were also performed to illustrate the versatility of these building blocks.

Synthesis of combretastatin D-2. An efficient route to caffrane macrolactones

Combretastatin D-2, (1), was synthesized via a 10 step sequence. Macrolactonization was performed saturated substrate 12 in high yield and the double bond was established via dehalogenation of intermediate 15.