157035-23-9

Upstream product

• 121651-99-8 (4S,5R)-4,5-O-isopropylidenedioxycyclohex-2-en-1-one 

Downstream Products

• 157035-24-0 (4S,5R)-5-allyl-4-(tert-butyldimethylsiloxy)cyclohex-2-enone 
• 157035-28-4 N-Benzyl-2-((4aR,5R,8aR)-2-benzyl-5-hydroxy-8-oxo-octahydro-isoquinolin-8a-yl)-N-(4-methoxy-benzyl)-acetamide 
• 157035-32-0 (4aR,7aR,10aR)-8-Benzyl-5-benzyloxymethyl-7,9-dioxo-3,4,4a,7,7a,8,9,10-octahydro-pyrrolo[2,3-i]isoquinoline-2-carboxylic acid methyl ester 
• 157035-26-2 N-Benzyl-2-[(1R,2R,3R)-3-(tert-butyl-dimethyl-silanyloxy)-6-oxo-2-(2-oxo-ethyl)-cyclohexyl]-N-(4-methoxy-benzyl)-acetamide 
• 157035-29-5 (4aR,5R,10aR)-8-Benzyl-5-methoxycarbonyloxy-9-oxo-3,4,4a,5,6,8,9,10-octahydro-pyrrolo[2,3-i]isoquinoline-2-carboxylic acid methyl ester 
• 157035-25-1 2-[(1R,2R,3R)-2-Allyl-3-(tert-butyl-dimethyl-silanyloxy)-6-oxo-cyclohexyl]-N-benzyl-N-(4-methoxy-benzyl)-acetamide 
• 157035-30-8 (4aS,7aR,10aR)-8-Benzyl-7,9-dioxo-3,4,4a,7,7a,8,9,10-octahydro-pyrrolo[2,3-i]isoquinoline-2-carboxylic acid methyl ester 

Relevant academic research and scientific papers

A versatile access to enantiomerically pure 5-substituted 4-hydroxycyclohex-2-enones: An advanced hemisecalonic acid a model

A convenient route for the versatile preparation of 5-substituted 4-hydroxycyclohex-2-enones via the addition of an organocuprate to a cyclohex-2-enone is reported. These compounds are important intermediates in our synthetic studies towards the mycotoxin