157035-24-0

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 157035-23-9 (3R,4S,5R)-5-allyl-3,4-(isopropylidenedioxy)cyclohexanone 
• 864155-60-2 (1S,4R,4aS,7R,8S,8aR)-7-Allyl-8-(tert-butyl-dimethyl-silanyloxy)-4,4a,6,7,8,8a-hexahydro-1H-1,4-methano-naphthalen-5-one 
• 864155-59-9 (1S,4R,4aS,5R,8S,8aR)-5-Allyl-8-(tert-butyl-dimethyl-silanyloxy)-1,4,4a,5,8,8a-hexahydro-1,4-methano-naphthalen-5-ol 
• 51175-59-8 norbornenoquinone 
• 678197-26-7 tricyclo[6.2.1.0^2,7]undeca-4,9-diene-3,6-diol 
• 121651-99-8 (4S,5R)-4,5-O-isopropylidenedioxycyclohex-2-en-1-one 
• 162662-48-8 (1S,4R,4aS,8S,8aR)-8-(tert-Butyl-dimethyl-silanyloxy)-4,4a,8,8a-tetrahydro-1H-1,4-methano-naphthalen-5-one 
• 146830-36-6 (+)-(1S,4R,4aS,5R,8S,8aR)-5-Acetoxy-1,4,4a,5,8,8a-hexahydro-8-hydroxy-endo-1,4-methanonaphthalene 
• 146830-46-8 Acetic acid (1S,4R,4aS,5R,8S,8aR)-8-(tert-butyl-dimethyl-silanyloxy)-1,4,4a,5,8,8a-hexahydro-1,4-methano-naphthalen-5-yl ester 
• 146830-47-9 (1S,4R,4aS,5R,8S,8aR)-8-(tert-Butyl-dimethyl-silanyloxy)-1,4,4a,5,8,8a-hexahydro-1,4-methano-naphthalen-5-ol 

Downstream Products

• 181230-63-7 (3R,4R)-4-tert-butyldimethylsiloxy-3-(2-propenyl)cyclohexanone 
• 157035-28-4 N-Benzyl-2-((4aR,5R,8aR)-2-benzyl-5-hydroxy-8-oxo-octahydro-isoquinolin-8a-yl)-N-(4-methoxy-benzyl)-acetamide 
• 157035-32-0 (4aR,7aR,10aR)-8-Benzyl-5-benzyloxymethyl-7,9-dioxo-3,4,4a,7,7a,8,9,10-octahydro-pyrrolo[2,3-i]isoquinoline-2-carboxylic acid methyl ester 
• 157035-26-2 N-Benzyl-2-[(1R,2R,3R)-3-(tert-butyl-dimethyl-silanyloxy)-6-oxo-2-(2-oxo-ethyl)-cyclohexyl]-N-(4-methoxy-benzyl)-acetamide 
• 157035-29-5 (4aR,5R,10aR)-8-Benzyl-5-methoxycarbonyloxy-9-oxo-3,4,4a,5,6,8,9,10-octahydro-pyrrolo[2,3-i]isoquinoline-2-carboxylic acid methyl ester 
• 157035-30-8 (4aS,7aR,10aR)-8-Benzyl-7,9-dioxo-3,4,4a,7,7a,8,9,10-octahydro-pyrrolo[2,3-i]isoquinoline-2-carboxylic acid methyl ester 
• 864155-65-7 [(1R,2S,5R,6R)-6-Allyl-5-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxy)-cyclohex-3-enyl]-acetic acid (S)-1-methyl-but-3-enyl ester 
• 864155-66-8 (Z)-(1R,4S,4aR,8S,12aR)-1-(tert-Butyl-dimethyl-silanyloxy)-4-(tert-butyl-diphenyl-silanyloxy)-8-methyl-1,4,4a,5,8,9,12,12a-octahydro-7-oxa-benzocyclodecen-6-one 
• 864155-64-6 [6-allyl-5-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxy)-cyclohex-3-enyl]-acetic acid ethyl ester 
• 864155-68-0 (4S,4aR,8S,12aR)-4-(tert-Butyl-diphenyl-silanyloxy)-8-methyl-decahydro-7-oxa-benzocyclodecene-1,6-dione 
• 864155-70-4 (Z)-(1R,4S,4aR,8S,12aR)-4-(tert-Butyl-diphenyl-silanyloxy)-1-hydroxy-8-methyl-1,4,4a,5,8,9,12,12a-octahydro-7-oxa-benzocyclodecen-6-one 
• 864155-67-9 (Z)-(4S,4aR,8S,12aR)-4-(tert-Butyl-diphenyl-silanyloxy)-8-methyl-4a,5,8,9,12,12a-hexahydro-4H-7-oxa-benzocyclodecene-1,6-dione 

Relevant academic research and scientific papers

Enantioselective total synthesis of bioactive natural product (+)-Sch 642305: A structurally novel inhibitor of bacterial DNA primase and HIV-1 Tat transactivation

The total synthesis of the bioactive natural product (+)-Sch 642305 has been achieved from a readily available chiral building block using an RCM protocol to construct the key decalactone moiety; our approach is notable for its built-in flexibility and is

A versatile access to enantiomerically pure 5-substituted 4-hydroxycyclohex-2-enones: An advanced hemisecalonic acid a model

A convenient route for the versatile preparation of 5-substituted 4-hydroxycyclohex-2-enones via the addition of an organocuprate to a cyclohex-2-enone is reported. These compounds are important intermediates in our synthetic studies towards the mycotoxin

An Enantioselective Approach to the Synthesis of Manzamine A

A new approach for asymmetric construction of the pyrroloisoquinoline core of manzamine A is described.The synthesis starts with D-(-)-quinic acid and features an intermolecular Mannich reaction as the central step.