157065-79-7Relevant academic research and scientific papers
Nondirected Copper-Catalyzed Sulfoxidations of Benzylic C-H Bonds
Yu, Hao,Li, Zhen,Bolm, Carsten
supporting information, p. 2076 - 2079 (2018/04/16)
A copper-catalyzed sulfoxidation of benzylic C-H bonds by nondirected oxidative C(sp3)-H activation was developed. The process proceeds via sulfenate anions, which are generated by base-triggered elimination of β-sulfinyl esters and benzyl radicals. The functional group tolerance is high, and the product yields are good.
Copper-catalyzed asymmetric oxidation of sulfides
O'Mahony, Graham E.,Ford, Alan,Maguire, Anita R.
body text, p. 3288 - 3296 (2012/05/20)
Copper-catalyzed asymmetric sulfoxidation of aryl benzyl and aryl alkyl sulfides, using aqueous hydrogen peroxide as the oxidant, has been investigated. A relationship between the steric effects of the sulfide substituents and the enantioselectivity of th
A combined theoretical and experimental investigation on the enantioselective oxidation of aryl benzyl sulfides in the presence of a chiral titanium catalyst
Naso, Francesco,Capozzi, Maria Annunziata M.,Bottoni, Andrea,Calvaresi, Matteo,Bertolasi, Valerio,Capitellil, Francesco,Cardellicchio, Cosimo
experimental part, p. 13417 - 13426 (2010/06/16)
An experimental investigation of the enantioselective oxidation of aryl benzyl sulfides by tert-butyl hydroperoxide in the presence of a titanium/hydrobenzoin catalyst has shown that these sulfides are ideal substrates for this catalytic system, with negl
