157166-42-2Relevant academic research and scientific papers
Photoinduced Electron Transfer Reaction of Cyclopropanone Acetals with Arylmethyl Methanesulfonate: Generation of β-Keto Radical Species and Application to C-C Bond Formation
Abe, Manabu,Oku, Akira
, p. 1673 - 1674 (1994)
The photoinduced electron transfer reaction of the cyclopropanone acetals 1 with arylmethyl methanesulfonates 4 or 10 as electron acceptors was found to generate a transient pair of radicals, the β-keto radical 3 and the arylmethyl radical, which underwent a novel carbon-carbon formation reaction at the sterically hindered β-position of the esters.
