Journal of the Chemical Society. Chemical communications p. 1673 - 1674 (1994)
Update date:2022-08-05
Topics:
Abe, Manabu
Oku, Akira
The photoinduced electron transfer reaction of the cyclopropanone acetals 1 with arylmethyl methanesulfonates 4 or 10 as electron acceptors was found to generate a transient pair of radicals, the β-keto radical 3 and the arylmethyl radical, which underwent a novel carbon-carbon formation reaction at the sterically hindered β-position of the esters.
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