15717-55-2Relevant academic research and scientific papers
Total stereochemical control in the addition of thiols to p-toluenesulfonylacetylene. Synthesis of Z-and E-2-sulfanylvinylsulfonyl derivatives
Medel, Rocio,Monterde, Maria I.,Plumet, Joaquin,Rojas, Jenny K.
, p. 735 - 738 (2007/10/03)
(Chemical Equation Presented) Alkyl and aryl sulfides react with equimolecular amounts of p-toluenesulfonylacetylene in CH3CN at 0°C or rt without the use of any catalytic reagent to give good yields of Z-2-sulfanylvinylsulfonyl derivatives wit
NUCLEOPHILIC REACTION AT A VINYL CENTER. XXII. SYNTHESIS AND NUCLEOPHILIC VINYLIC SUBSTITUTION IN E-β-FLUOROVINYL ARYL SULFONES
Shainyan, B. A.,Mirskova, A. N.
, p. 61 - 66 (2007/10/02)
The reaction of potassium fluoride with E-β-bromovinyl aryl sulfones in the presence of 18-crown-6-ether leads to a mixture of the sulfones XC6H4SO2CH2CHF2 and E-XC6H4SO2CH=CHF, the ratio of which decreases in the order X=CH3, H, Cl, NO2.The kinetics of n
SELENOSULFONATION OF ACETYLENES. SUBSTITUTION REACTIONS OF β-(PHENYLSELENO)VINYL SULFONES WITH ORGANOCUPRATES
Back, Thomas G.,Collins, Scott,Law, Kwok-Wai
, p. 1689 - 1692 (2007/10/02)
β-(Phenylseleno)vinyl sulfones are readily available from the selenosulfonation of acetylenes and undergo efficient, stereoselective substitution of the phenylseleno moiety by the alkyl group of alkyl (phenylseleno)cuprates.
