1571900-77-0

Upstream product

• 1571900-72-5 (2R,3R,E)-6-(tert-butyldimethylsilyloxy)-2-(4-methoxybenzyloxy)hex-4-en-3-ol 
• 1571900-66-7 (4R,5R,E)-5-(4-methoxybenzyloxy)hex-2-ene-1,4-diol 
• 27948-61-4 (R)-(+)-1-(2-furyl)ethanol 
• 1571900-75-8 (1R,2R)-1-((1S,2S)-2-((tert-butyldimethylsilyloxy)methyl)cyclopropyl)-2-(4-methoxybenzyloxy)propan-1-ol 
• 107-30-2 chloromethyl methyl ether 
• 1192-62-7 1-(2-furyl)-1-ethanone 
• 1571900-61-2 (R)-2-(1-(4-methoxybenzyloxy)ethyl)furan 
• 1571900-63-4 (R,E)-5-(4-methoxybenzyloxy)-4-oxohex-2-enal 

Downstream Products

• 1571900-78-1 ((1S,2S)-2-((1R,2R)-2-(4-methoxybenzyloxy)-1-(methoxymethoxy)propyl)cyclopropyl)methanol 
• 1571900-84-9 (E)-ethyl 3-((1R,2S)-2-((1R,2R)-2-(4-methoxybenzyloxy)-1-(methoxymethoxy)propyl)cyclopropyl)acrylate 
• 1571900-81-6 C₁₇H₂₄O₅ 
• 1571900-85-0 C₁₉H₂₈O₅ 
• 1571900-87-2 ((2S,3S)-3-((1S,2S)-2-((1R,2R)-2-(4-methoxybenzyloxy)-1-(methoxymethoxy)propyl)cyclopropyl)oxiran-2-yl)methanol 
• 1571900-89-4 ((2R,3R)-3-((1S,2S)-2-((1R,2R)-2-(4-methoxybenzyloxy)-1-(methoxymethoxy)propyl)cyclopropyl)oxiran-2-yl)methanol 
• 1571900-93-0 (R)-4-((S)-hydroxy((1S,2S)-2-((1R,2R)-2-(4-methoxybenzyloxy)-1-(methoxymethoxy)propyl)cyclopropyl)methyl)-1,3-dioxolan-2-one 
• 1571901-01-3 (1S,2R)-1-(tert-butyldimethylsilyloxy)-1-((1S,2S)-2-((1R,2R)-2-(4-methoxybenzyloxy)-1-(methoxymethoxy)propyl)cyclopropyl)-but-3-en-2-yl but-3-enoate 
• 1571901-02-4 (R)-6-((S)-(tert-butyldimethylsilyloxy)((1S,2S)-2-((1R,2R)-2-(4-methoxybenzyloxy)-1-(methoxymethoxy)propyl)cyclopropyl)-methyl)-3,6-dihydro-2H-pyran-2-one 
• 1571901-03-5 (R)-6-((S)-(tert-butyldimethylsilyloxy)((1S,2S)-2-((1R,2R)-2-(4-methoxybenzyloxy)-1-(methoxymethoxy)propyl)cyclopropyl)-methyl)-5,6-dihydro-2H-pyran-2-one 
• 1571901-08-0 (E)-((1R,2R)-1-((1S,2S)-2-((S)-(tert-butyldimethylsilyloxy)((R)-6-oxo-3,6-dihydro-2H-pyran-2-yl)methyl)cyclopropyl)-1-hydroxypropan-2-yl) 3-(4-methoxyphenyl)acrylate 
• 1571901-06-8 C₃₀H₄₄O₈Si 
• 1571901-10-4 (E)-((1R,2R)-1-hydroxy-1-((1S,2S)-2-((S)-hydroxy((R)-6-oxo-3,6-dihydro-2H-pyran-2-yl)methyl)cyclopropyl)propan-2-yl) 3-(4-methoxyphenyl)acrylate 

Relevant academic research and scientific papers

Towards the diastereoselective synthesis of derivative of 11′-epi-brevipolide H

An efficient diastereoselective synthesis of brevipolide H derivative is described. The approach features the use of (i) catalytic asymmetric transfer hydrogenation, (ii) hydroxyl-directed cyclopropanation, and (iii) substrate-controlled catalytic epoxidation and ring-closing metathesis. Remarkably, in this convergent synthesis process, stereogenic centers were installed through catalytic reactions with high stereocontrol, which greatly facilitates the synthesis of stereo-divergent derivatives.