1572191-75-3Relevant academic research and scientific papers
Synergistic catalysis of the Br?nsted acid and highly dispersed Cu on the mesoporous Beta zeolite in the intermolecular aminoazidation of styrene
Fu, Wenqian,Yin, Chengyou,Feng, Yu,Zhang, Lei,Cheng, Feng,Fang, Zhongxue,Zhu, Chaojie,Tang, Tiandi
, (2021)
Acidic mesoporous Beta zeolite supported Cu (Cu/Beta-M) catalyst shows superior catalytic performance in the difunctionalization of styrenes with N-fluorobenzenesulfonimide (F-N(SO2Ph)2) and azidotrimethylsilane, compared with basic
Copper-catalyzed intermolecular aminoazidation of alkenes
Zhang, Bo,Studer, Armido
supporting information, p. 1790 - 1793 (2014/04/17)
Copper-catalyzed intermolecular aminoazidation of alkenes is described. This novel methodology provides an efficient approach to vicinal amino azides which can easily be transformed into other valuable amine derivatives. The commercially available N-fluorobenzenesulfonimide (NFSI) is used as a nitrogen-radical precursor and TMSN3 as the N3 source. Yields are moderate to excellent, and for internal alkenes aminoazidation occurs with excellent diastereoselectivity.
