15727-82-9

Basic information

• Product Name: allyl 2-(p-tolyl)acetate
• Synonyms: allyl 2-(p-tolyl)acetate
• CAS NO: 15727-82-9
• Molecular Weight: 190.242
• Mol File: 15727-82-9.mol

Chemical Properties

• CAS DataBase Reference: allyl 2-(p-tolyl)acetate(CAS DataBase Reference)
• NIST Chemistry Reference: allyl 2-(p-tolyl)acetate(15727-82-9)
• EPA Substance Registry System: allyl 2-(p-tolyl)acetate(15727-82-9)

Safety Data

• Hazardous Substances Data: 15727-82-9(Hazardous Substances Data)

Upstream product

• 80735-94-0 1-Phenyl-3-buten-1-ol 
• 622-47-9 4-tolylacetic acid 

Downstream Products

• 1360924-11-3 allyl 2-oxo-2-(p-tolyl)acetate 

Relevant articles and documents

Palladium-catalyzed allylic esterification via C-C bond cleavage of a secondary homoallyl alcohol

Palladium-catalyzed allylic esterifications of secondary homoallyl alcohols with acids via sequential retro-allylation and esterification are demonstrated, affording the corresponding allyl ester in up to 99% yield. The electron effect of the substituent of the secondary alcohol was found to be crucial to the selective C-C bond cleavage.