15729-19-8Relevant academic research and scientific papers
Rhodium-catalyzed asymmetric hydroarylation of diphenylphosphinylallenes with arylboronic acids
Nishimura, Takahiro,Hirabayashi, Sho,Yasuhara, Yuichi,Hayashi, Tamio
, p. 2556 - 2557 (2006)
Rhodium-catalyzed asymmetric hydroarylation of diphenylphosphinylallenes with arylboronic acids proceeded in high yields with high regio- and enantioselectivity to give chiral allylphosphine oxides of up to 98% ee. The structural determination of the key
Direct Access to Allenylphosphine Oxides via a Metal Free Coupling of Propargylic Substrates with P(O)H Compounds
Yang, Chun-Hua,Fan, Huihui,Li, Huimin,Hou, Shenyin,Sun, Xiangkun,Luo, Donghao,Zhang, Yinchao,Yang, Zhantao,Chang, Junbiao
supporting information, p. 9438 - 9441 (2019/11/20)
A direct and convenient approach for the coupling of propargylic substrates with diphenylphosphine oxide in the presence of Tf2O and 2,6-lutidine has been developed. The method provides a general approach for the construction of attractive allenylphosphoryl skeletons with high atom and step economy under metal free conditions.
Neighboring group participation of phosphine oxide functionality in the highly regio- and stereoselective iodohydroxylation of 1,2-allenylic diphenyl phosphine oxides
Guo, Hao,Qian, Rong,Guo, Yinlong,Ma, Shengming
, p. 7934 - 7938 (2008/12/22)
(Chemical Equation Presented) Two sets of reaction conditions were established to enable the highly regio- and stereoselective iodohydroxylation of 1,2-allenylic diphenyl phosphine oxides, yielding (E)-2-iodo-3-hydroxy-1- alkenyl diphenyl phosphine oxides
Highly regiocontrolled pd-catalyzed cross-coupling reaction of terminal alkynes and allenylphosphine oxides
Rubin, Michael,Markov, Jelena,Chuprakov, Stepan,Wink, Donald J.,Gevorgyan, Vladimir
, p. 6251 - 6256 (2007/10/03)
The cross-coupling of a variety of terminal alkynes 1 with allenylphosphine oxides 2 catalyzed by a Pd(OAc)2-TDMPP system provided conjugated endo-enynes 3 solely, while the TCPC-catalyzed reaction of the same regents led to the exclusive forma
