157372-80-0Relevant articles and documents
Synthesis of the Tricyclo3,8>pentadecane (ABC) Ring System of Taxane Diterpenes
Romero, Miguel A.,Franco, Ruben Perez,Cruz-Almanza, Raymundo,Padilla, Fernando
, p. 3255 - 3258 (2007/10/02)
The synthesis of diketone 14 possessing the tricyclo3,8>pentadecane (ABC) taxane ring system is described.This concise approach employs a Wacker oxidation, intramolecular aldol condensation-dehydration, and a highly exo-stereoselective