36040-02-5

Upstream product

• 1125-99-1 1-(1-Cyclohexen-1-yl)pyrrolidine 
• 3066-75-9 allyl diethyl phosphate 
• 591-87-7 Allyl acetate 
• 108-94-1 cyclohexanone 
• 92954-34-2 N,N'-dicyclohexyl-O-allylisourea 
• 5453-93-0 allyl 2-oxocyclohexane-1-carboxylate 
• 1746-13-0 allyl phenyl ether 
• 24738-82-7 (S)-1-Cyclohex-1-enyl-pyrrolidine-2-carboxylic acid ethyl ester 
• 92954-34-2 2-allyl-1,3-dicyclohexylisourea 
• 557-40-4 Allyl ether 
• 6407-35-8 N-cyclohexylidenemethylamine 
• 592-88-1 diallyl sulphide 
• 999-55-3 allyl acrylate 
• 96-05-9 allyl methacrylate 

Downstream Products

• 72490-29-0 2,6-Dipropyl-cyclohexanon 
• 97029-34-0 2,6-Dipropyl-cyclohexanol 

Relevant academic research and scientific papers

Organic Compounds

Described are spiroalkyl- and -alkenylketones and esters thereof, a method for their production and fragrance compositions comprising them.

Synthesis of the Tricyclo3,8>pentadecane (ABC) Ring System of Taxane Diterpenes

The synthesis of diketone 14 possessing the tricyclo3,8>pentadecane (ABC) taxane ring system is described.This concise approach employs a Wacker oxidation, intramolecular aldol condensation-dehydration, and a highly exo-stereoselective

2-Allylisourea as an Effective Agent for Direct α-Allylation of Ketone and Aldehyde Assisted by Palladium(0) under Neutral Conditions

Direct α-allylation of a variety of ketones and aldehydes with 2-allylisourea took place in the presence of a catalytic amount of a palladium(0) complex under neutral and mild conditions.Scope and limitations of this novel method have been investigated.

Palladium-catalysed Asymmetric Allylations by a Chiral Allyl Ester; the Palladium Catalysis of (S)-Proline Allyl Ester Enamines

The palladium-catalysed allylation of the chiral enamines (1a-d) followed by acidic hydrolysis, produced optically active 2-allylcyclohexanone (2); the catalysis of the chiral enamine (1a), derived from (S)-proline allyl ester, with tetrakis(triphenyl pho

NUCLEOPHILIC SUBSTITUTION REACTIONS OF ALLYLIC ESTERS CATALYSED BY PALLADIUM-GRAPHITE AND RELATED HETEROGENEOUS CATALYSTS

Highly dispersed palladium on graphite (Pd/Gr), carbon (Pd/C) and alumina (Pd/Al2O3) have been employed as catalysts in substitution reactions of allylic esters with nucleophiles such as benzenesulfinate and diethyl malonate anions, and 1-(1-cyclohexen-1-yl)pyrrolidine.

DIRECT Α-ALLYLATION OF KETONES WITH O-ALLYLISOUREA CATALYZED BY PALLADIUM(0)

Direct α-allylation of ketones catalyzed by a palladium(0)-diphosphine system took place employing O-allylisourea as the allylating reagent under neutral conditions ar room temperature in DMF.

SYNTHESIS OF γ,δ-UNSATURATED KETONES BY THE INTRAMOLECULAR DECARBOXYLATIVE ALLYLATION OF ALLYL β-KETO CARBOXYLATES AND ALKENYL ALLYL CARBONATES CATALYZED BY MOLYBDENUM, NICKEL, AND RHODIUM COMPLEXES

Allyl β-keto carboxylates and alkenyl allyl carbonates were converted to γ,δ-unsaturated ketones by the intramolecular decarboxylative allylation catalyzed by molybdenum, nickel, and rhodium complexes.