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14-Epi stereoisomers of 25-hydroxy- and 1α,25-dihydroxyvitamin D3: Synthesis, isomerization to previtamins, and biological studies
Maynard,Trankle,Norman,Okamura
, p. 2387 - 2393 (1994)
The C-14 epimers of vitamin D, 14-epi-25-hydroxyvitamin D3 (4) and 14- epi-1α,25-dihydroxyvitamin D3 (5), were synthesized, and their isomerization via [1,7]-sigmatropic hydrogen shifts to the corresponding previtamin forms (4' and 5
