14-Epi stereoisomers of 25-hydroxy- and 1α,25-dihydroxyvitamin D3: Synthesis, isomerization to previtamins, and biological studies

DOI: 10.1021/jm00041a017

Source and publish data:

Journal of Medicinal Chemistry p. 2387 - 2393 (1994)

Update date:2022-08-03

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Authors:

Maynard Maynard

Trankle Trankle

Norman Norman

Okamura Okamura

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Article abstract of DOI:10.1021/jm00041a017

The C-14 epimers of vitamin D, 14-epi-25-hydroxyvitamin D₃ (4) and 14- epi-1α,25-dihydroxyvitamin D₃ (5), were synthesized, and their isomerization via [1,7]-sigmatropic hydrogen shifts to the corresponding previtamin forms (4' and 5

Full text of DOI:10.1021/jm00041a017

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