157381-44-7Relevant academic research and scientific papers
Zirconium-BINOLate-catalyzed, enantioselective aldol-Tishchenko reactions of aromatic ketone aldols
Schneider, Christoph,Hansch, Markus,Sreekumar, Pankajakshan
, p. 2738 - 2742 (2006)
3,3′-Substituted BINOL's have been identified as suitable chiral ligands for the zirconium-catalyzed aldol-Tishchenko reaction of aromatic ketone aldols with aliphatic aldehydes. 1,3-anti-Diol monoesters were obtained in excellent yields, complete anti-diastereocontrol, and enantioselectivities of up to 60% ee.
Synthesis of anti-l,3-Diols through RuCl3/PPh3-Mediated Hydrogenation of β-Hydroxy Ketones: An alternative to organoboron reagents
Roche, Christophe,Labeeuw, Olivier,Haddad, Mansour,Ayad, Tahar,Genet, Jean-Pierre,Virginie, Ratovelomanana-Vidal,Phansavath, Phannarath
scheme or table, p. 3977 - 3986 (2010/02/27)
Hydrogenation of enantioenriched β-hydroxy ketones promoted by the catalyst generated in situ from commercially available and inexpensive RuCl 3 and PPh3 under hydrogen pressure allowed the efficient preparation of a variety of anti1
