157384-67-3Relevant academic research and scientific papers
Reactivity patterns of H2 and CO with a rhodium(II) salen derivative: Formation of hydride, formyl, and dimetal ketone complexes and rhodium reduction
Bunn, Andrew G.,Wei, Mingli,Wayland, Bradford B.
, p. 3390 - 3392 (1994)
A benzene soluble dimeric rhodium(II) salen derivative, [(ttbs)Rh]2, with a weak Rh-Rh bond (13 kcal mol-1) reacts with H2 and CO to produce hydride, metalloketone, and formyl complexes, but reaction of (ttbs)Rh-H with CO also induces migration of H+ from rhodium to the salen ligand to form a rhodium(I) dicarbonyl complex, (Httbs)Rh(CO)2.
