Reactivity patterns of H2 and CO with a rhodium(II) salen derivative: Formation of hydride, formyl, and dimetal ketone complexes and rhodium reduction

DOI: 10.1021/om00021a006

Source and publish data:

Organometallics p. 3390 - 3392 (1994)

Update date:2022-08-03

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Authors:

Bunn, Andrew G.

Wei, Mingli

Wayland, Bradford B.

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Article abstract of DOI:10.1021/om00021a006

A benzene soluble dimeric rhodium(II) salen derivative, [(ttbs)Rh]₂, with a weak Rh-Rh bond (13 kcal mol^-1) reacts with H₂ and CO to produce hydride, metalloketone, and formyl complexes, but reaction of (ttbs)Rh-H with CO also induces migration of H⁺ from rhodium to the salen ligand to form a rhodium(I) dicarbonyl complex, (Httbs)Rh(CO)₂.

Full text of DOI:10.1021/om00021a006

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