Organometallics p. 3390 - 3392 (1994)
Update date:2022-08-03
Topics:
Bunn, Andrew G.
Wei, Mingli
Wayland, Bradford B.
A benzene soluble dimeric rhodium(II) salen derivative, [(ttbs)Rh]2, with a weak Rh-Rh bond (13 kcal mol-1) reacts with H2 and CO to produce hydride, metalloketone, and formyl complexes, but reaction of (ttbs)Rh-H with CO also induces migration of H+ from rhodium to the salen ligand to form a rhodium(I) dicarbonyl complex, (Httbs)Rh(CO)2.
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Doi:10.1002/prac.19983400511
(1998)Doi:10.1016/S0040-4039(00)73310-7
(1994)Doi:10.1016/j.chembiol.2021.01.023
(2021)Doi:10.1016/j.tetlet.2013.12.062
(2014)Doi:10.1021/np4009046
(2014)Doi:10.1021/ol403634b
(2014)
