1574184-77-2Relevant articles and documents
Terminal aryl alkenes and alkynes as arylcarboxy surrogates toward o -Benzoxylation of 2-phenylpyridine catalyzed by copper
Rout, Saroj Kumar,Guin, Srimanta,Gogoi, Anupal,Majji, Ganesh,Patel, Bhisma K.
supporting information, p. 1614 - 1617 (2014/04/17)
A variety of styrenes and phenylacetylenes serve as excellent arylcarboxy sources in bringing about substrate directed o-benzoxylation of 2-phenylpyridine derivatives catalyzed by Cu(II) in the presence of TBHP. This reaction proceeds via formation of phenylglyoxal followed by decarbonylation to benzoyl radical/benzaldehyde which acts as the arylcarboxy source.