15747-15-6Relevant academic research and scientific papers
Siliciumhaltige Carben-Komplexe VIII. HSiR3-Eliminierung aus Carben-Komplexen des Types (CO)5MC(NHR')SiR3 (M= Cr, Mo, W)
Hepp, Wolfgang,Schubert, Ulrich
, p. 317 - 326 (1987)
Upon heating solid monoalkylamino(silyl)carbene complexes (CO)5MC(NHR')SiR3 (M= W: SiR3= SiPh3, R'= Me, Et, n-Bu, C6H11, Ph; SiR3= SiMePh2, R'= Me, Et.M=Mo, Cr: R=Ph, R'= Me, Et) beyond their melting points, HSiR3 elimination with formation of the isonitr
