Siliciumhaltige Carben-Komplexe VIII. HSiR3-Eliminierung aus Carben-Komplexen des Types (CO)5MC(NHR')SiR3 (M= Cr, Mo, W)

DOI: 10.1016/0022-328X(87)80303-0

Source and publish data:

Journal of Organometallic Chemistry p. 317 - 326 (1987)

Update date:2022-08-04

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Authors:

Hepp, Wolfgang

Schubert, Ulrich

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Article abstract of DOI:10.1016/0022-328X(87)80303-0

Upon heating solid monoalkylamino(silyl)carbene complexes (CO)5MC(NHR')SiR3 (M= W: SiR3= SiPh3, R'= Me, Et, n-Bu, C6H11, Ph; SiR3= SiMePh2, R'= Me, Et.M=Mo, Cr: R=Ph, R'= Me, Et) beyond their melting points, HSiR3 elimination with formation of the isonitr

Full text of DOI:10.1016/0022-328X(87)80303-0

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