157552-28-8

Basic information

• Product Name: iso-β-cyclocitral
• Synonyms: iso-β-cyclocitral
• CAS NO: 157552-28-8
• Molecular Weight: 152.236
• Mol File: 157552-28-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: iso-β-cyclocitral(CAS DataBase Reference)
• NIST Chemistry Reference: iso-β-cyclocitral(157552-28-8)
• EPA Substance Registry System: iso-β-cyclocitral(157552-28-8)

Safety Data

• Hazardous Substances Data: 157552-28-8(Hazardous Substances Data)

Upstream product

• 433267-90-4 5,5-dimethyl-1,4,5,6,7,8-hexahydro-2,3-benzodioxine 
• 54345-56-1 (8,8-dimethyl-4-methylene)-1-oxaspiro<2.5>octane 
• 60714-17-2 1,1-dimethyl-2,3-bis(methylene)cyclohexane 
• 73410-07-8 1-hydroxymethyl-2-methylene-3,3-dimethylcyclohexane 
• 157552-19-7 1,6,6,-trimethyl-2-methylenecyclohexan-1-ol 

Relevant articles and documents

Functionality of γ- and δ-pyrorenes. Synthesis and study of the reactivity of peroxide compounds

The photooxygenation of γ- and δ-pyronenes, performed for the first time, affords, as expected, a hydroperoxide, a hydroperoxyperoxide, and an endoperoxide, respectively. The reactivity of these peroxides is studied. They lead to mono-, di- or trifunctional compounds. Most of them are new and could be useful to synthesize molecules with potential sweet-smelling or therapeutic properties.

Epoxy-pyronene: Obtention of cyclocitrals from ionones and precursor of new terpenic compounds

The selective obtention of epoxy-pyronene from δ-pyronene has been realized using metachloroperbenzoic acid. The isomerization of this epoxidic compound with Lewis and protonic acids and on active alumina has been studied leading to cyclocitrals. Ionones are obtained from epoxy-pyronene by homologation with various C3 units, in the presence of paratoluenesulfonic acid in order to obtain β-cyclocitral in situ. New terpenic compounds with the cyclogeranyl skeleton were obtained from epoxy-pyronene by reduction followed by homologation.