1575815-06-3Relevant academic research and scientific papers
Palladium(0)-catalyzed cyclopropanation of benzyl bromides via C(sp 3)-H bond activation
Mao, Jiangang,Zhang, Shuo-Qing,Shi, Bing-Feng,Bao, Weiliang
, p. 3692 - 3694 (2014/04/03)
A novel and highly efficient Pd(0)-catalyzed domino reaction to prepare cyclopropane derivatives has been established. The process involves a Heck-type coupling reaction and a C(sp3)-H bond activation. Preliminary DFT calculations suggest that a four-membered palladacycle intermediate is involved. This journal is the Partner Organisations 2014.
