2,2'',4,4'',6,6''-hexamethyl-[1,1':3',1''-terphenyl]-2'-thiol

Base Information

• Chemical Name: 2,2'',4,4'',6,6''-hexamethyl-[1,1':3',1''-terphenyl]-2'-thiol
• CAS No.: 157590-41-5
• Molecular Formula: C₂₄H₂₆S
• Molecular Weight: 346.536
• Mol file: 157590-41-5.mol

Synonyms:2,2'',4,4'',6,6''-hexamethyl-[1,1':3',1''-terphenyl]-2'-thiol

Chemical Property of 2,2'',4,4'',6,6''-hexamethyl-[1,1':3',1''-terphenyl]-2'-thiol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,2'',4,4'',6,6''-hexamethyl-[1,1':3',1''-terphenyl]-2'-thiol

There total 1 articles about 2,2'',4,4'',6,6''-hexamethyl-[1,1':3',1''-terphenyl]-2'-thiol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

(DME)Fe(SDmp)(Mes) → bimesityl (4482-03-5) + (Mes)Fe(μ-SDmp)(μ-SDmp)Fe + 2,2'',4,4'',6,6''-hexamethyl-[1,1':3',1''-terphenyl]-2'-thiol (157590-41-5)

Guidance literature:

In diethyl ether; at 20 ℃; for 168h; Inert atmosphere;

DOI:10.1021/ic100692v

Reference yield: 82.0%

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) + 2,2'',4,4'',6,6''-hexamethyl-[1,1':3',1''-terphenyl]-2'-thiol (157590-41-5) + P(p-C6H4F)3 (18437-78-0) → [2,6-η6:η1-bis(2,4,6-trimethylphenyl)phenylthiolato]chlorido[tris(4-fluorophenyl)phosphine]ruthenium(II) (1420299-84-8)

Guidance literature:

2,2'',4,4'',6,6''-hexamethyl-[1,1':3',1''-terphenyl]-2'-thiol; With n-butyllithium; In hexane; at 0 ℃; for 0.5h;

[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; In tetrahydrofuran; hexane; at 0 - 20 ℃; for 3h;

P(p-C₆H₄F)3; In toluene; at 65 ℃; for 15h;

DOI:10.1021/ja311398j

Reference yield: 77.0%

C37H60FeN3S2Si2(1-)*C12H24KO6(1+) + 2,2'',4,4'',6,6''-hexamethyl-[1,1':3',1''-terphenyl]-2'-thiol (157590-41-5) → C55H67FeN2S3(1-)*C12H24KO6(1+)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 1.5h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.inorgchem.0c03427

Downstream raw materials:

Mo[SC₆H₃(C₆H₂(CH₃)3)2]3

Ni(2,6-((η2-mesityl)mesityl)phenylthiolate)(triphenylphosphine)

diphenyl(2,6-dimesitylphenylthio)bismuthine

Fe2(mesityl)2(μ-S-2,6-dimesitylphenyl)(μ-mesityl)