Welcome to LookChem.com Sign In|Join Free

CAS

  • or

157604-03-0

(E)-1-((1S,5R,7R)-10,10-Dimethyl-3,3-dioxo-3λ6-thia-4-aza-tricyclo[5.2.1.01,5]dec-4-yl)-3-[2-(2-methyl-[1,3]dioxolan-2-yl)-phenyl]-propenone is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

157604-03-0 Suppliers

Post Buying Request

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier

  • (E)-1-((1S,5R,7R)-10,10-Dimethyl-3,3-dioxo-3λ6-thia-4-aza-tricyclo[5.2.1.01,5]dec-4-yl)-3-[2-(2-methyl-[1,3]dioxolan-2-yl)-phenyl]-propenone

    Cas No: 157604-03-0

  • Need to discuss

  • No requirement

  • Adequate

  • TIANJIN ACCOUNTECH CO.,LTD.
  • Contact Supplier
  • 157604-03-0 Structure

  • Basic information

    1. Product Name: (E)-1-((1S,5R,7R)-10,10-Dimethyl-3,3-dioxo-3λ6-thia-4-aza-tricyclo[5.2.1.01,5]dec-4-yl)-3-[2-(2-methyl-[1,3]dioxolan-2-yl)-phenyl]-propenone
    2. Synonyms:
    3. CAS NO:157604-03-0
    4. Molecular Formula:
    5. Molecular Weight: 431.553
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 157604-03-0.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (E)-1-((1S,5R,7R)-10,10-Dimethyl-3,3-dioxo-3λ6-thia-4-aza-tricyclo[5.2.1.01,5]dec-4-yl)-3-[2-(2-methyl-[1,3]dioxolan-2-yl)-phenyl]-propenone(CAS DataBase Reference)
    10. NIST Chemistry Reference: (E)-1-((1S,5R,7R)-10,10-Dimethyl-3,3-dioxo-3λ6-thia-4-aza-tricyclo[5.2.1.01,5]dec-4-yl)-3-[2-(2-methyl-[1,3]dioxolan-2-yl)-phenyl]-propenone(157604-03-0)
    11. EPA Substance Registry System: (E)-1-((1S,5R,7R)-10,10-Dimethyl-3,3-dioxo-3λ6-thia-4-aza-tricyclo[5.2.1.01,5]dec-4-yl)-3-[2-(2-methyl-[1,3]dioxolan-2-yl)-phenyl]-propenone(157604-03-0)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 157604-03-0(Hazardous Substances Data)

157604-03-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 157604-03-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,5,7,6,0 and 4 respectively; the second part has 2 digits, 0 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 157604-03:
(8*1)+(7*5)+(6*7)+(5*6)+(4*0)+(3*4)+(2*0)+(1*3)=130
130 % 10 = 0
So 157604-03-0 is a valid CAS Registry Number.

157604-03-0Relevant articles and documents

Stereoselectivity and Generality of the Palladium-Catalysed Cyclopropanation of α,β-Unsaturated Carboxylic Acids Derivatized with Oppolzer's Sultam

Vallaerda, Jerk,Appelberg, Ulf,Csoeregh, Ingeborg,Hacksell, Uli

, p. 461 - 470 (2007/10/02)

A series of α,β-unsaturated carboxylic acids derivatized with camphorsultam 1 a s a chiral auxiliary has been stereoselectively cyclopropanated. the selectivity of the reaction produces cyclopropanated products with the 1R,2R absolute configuration as indicated by the optical rotations as well as by an X-ray structure determineation.The temperature dependence of the reaction was studied with three substrates. the highest stereoselectivity was obtained at temperatures above 25 deg C.Branching at the α- or β-carbons disfavours complete conversion, and electron-withdrawing substituents at these positions seem to prevent the reaction.The auxiliary was removed by using titanium(IV) isopropoxide in benzyl alcohol followed by alkaline hydrolysis of the intermediate ester. the potent 5-HT1A receptor agonist (1R,2S)-2-(2-hydroxyphenyl)-N,N-dipropylcyclopropylamine 13 was synthesized by this method

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 157604-03-0