157620-48-9

Upstream product

• 207501-95-9 (C₅H₅)Ru(CH₂(P(C₆H₅)2)2)(SC₁₀H₁₈O₆)⁽¹⁺⁾*BF₄^(1-)=[(C₅H₅)Ru(CH₂(P(C₆H₅)2)2)(SC₁₀H₁₈O₆)]BF₄ 
• 75-05-8 acetonitrile 
• 610320-14-4 (η5-cyclopentadienyl)Ru(η2-bis(diphenylphosphino)methane)H*(dichloromethane) 
• 41106-49-4 1-phenyl-3-azoniaspiro[2.4]heptane tetrafluoroborate 
• 872883-84-6 1,1-dimethyl-3-azoniaspiro[2.4]heptane tetrafluoroborate 
• 872883-87-9 1,1,2,2-tetramethylaziridinium tetrafluoroborate 
• 872883-90-4 1,1,2-trimethylaziridinium tetrafluoroborate 

Downstream Products

• 207502-02-1 [(C₅H₅)Ru(CH₂(P(C₆H₅)2)2)(sulfur dioxide)]BF₄ 

Relevant academic research and scientific papers

Ruthenium-catalyzed ionic hydrogenation of aziridinium cations

Hydride transfer from CpRu(dppm)H (dppm = bis(diphenylphosphino)methane) to asymmetrically substituted aziridinium cations occurs at the less substituted carbon when the substituents are alkyl, but at the more substituted carbon when the substituent is ph

Effect of chelate ring size on the rate of hydride transfer from CpRu(P-P)H (P-P = chelating diphosphine) to an iminium cation

The rate constants for hydride transfer from CpRu(P-P)H (P-P = bis(diphenylphosphino)-methane (dppm), bis(diphenylphosphino)ethane (dppe), bis(diphenylphosphino)benzene (dpbz), or bis(diphenylphosphino)propane (dppp)) to 1-(1-phenylethylidene)pyrrolidiniu

C-C Coupling Reactions of (Sulfene)ruthenium Complexes with Enolates

Sulfene complexes [CpRu(PR′3)2(RHC=SO2)]PF6 (2a-d) are obtained from the corresponding sulfur dioxide complexes 1a-c and diazomethane or -ethane. Reaction of [CpRu(dppm)(SO2)]Cl (1d) and phenyldiazomethane gives