157639-01-5

Basic information

• Product Name: (R)-5-methyl-2-(phenylthio)cyclohex-2-en-1-one
• Synonyms: (R)-5-methyl-2-(phenylthio)cyclohex-2-en-1-one
• CAS NO: 157639-01-5
• Molecular Weight: 218.32
• Mol File: 157639-01-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (R)-5-methyl-2-(phenylthio)cyclohex-2-en-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-5-methyl-2-(phenylthio)cyclohex-2-en-1-one(157639-01-5)
• EPA Substance Registry System: (R)-5-methyl-2-(phenylthio)cyclohex-2-en-1-one(157639-01-5)

Safety Data

• Hazardous Substances Data: 157639-01-5(Hazardous Substances Data)

Upstream product

• 790699-46-6 (R)-5-Methyl-2,2-bis-phenylsulfanyl-cyclohexanone 
• 88154-77-2 (5R)-5-methyl-2-(phenylsulfinyl)cyclohexan-1-one 
• 89-82-7 pulegone 
• 308358-04-5 (6R)-2,2,6-trimethyl-1-oxaspiro[2.5]octan-4-one 
• 882-33-7 diphenyldisulfane 
• 13368-65-5 (3R)-3-methylcyclohexanone 
• 101693-93-0 (5R)-5-methyl-2-(phenylthio)cyclohexan-1-one 

Downstream Products

• 476331-61-0 (1S,4R,5S,6S)-3-benzenesulfonyl-5-(tert-butyl-dimethyl-silanyloxy)-4,6-dimethyl-cyclohex-2-enol 
• 476331-51-8 (1S,2S,3S,6R)-5-benzenesulfonyl-2,6-dimethyl-cyclohex-4-ene-1,3-diol 
• 476331-60-9 (1S,2R,3R,6R)-5-benzenesulfonyl-2,6-dimethylcyclohex-4-ene-1,3-diol 
• 476331-59-6 (1R,2R,3S,6R)-5-benzenesulfonyl-2-methyl-7-oxa-bicyclo[4.1.0]hept-4-en-3-ol 
• 476331-57-4 (1S,2S,3R,5S,6S)-2-benzenesulfonyl-5-methyl-7-oxa-bicyclo[4.1.0]heptan-3-ol 
• 476331-52-9 (1R,5R)-2-benzenesulfonyl-5-methyl-cyclohex-2-enol 
• 476331-56-3 (1R,2R,5S)-2-benzenesulfonyl-5-methyl-cyclohex-3-enol 
• 476331-58-5 (1S,6S)-3-benzenesulfonyl-6-methylcyclohexa-2,4-dienol 
• 476331-54-1 ((S)-4-methyl-cyclohexa-1,5-dienesulfonyl)-benzene 
• 476331-55-2 (1S,5S,6S)-2-benzenesulfonyl-5-methyl-7-oxa-bicyclo[4.1.0]hept-2-ene 
• 476331-65-4 (1R,5R)-5-Methyl-2-phenylsulfanyl-cyclohex-2-enol 
• 790699-53-5 (R)-5-methyl-2-(phenylsulfinyl)cyclohex-2-en-1-one 
• 54307-83-4 (R)-(-)-3,5-dimethylcyclohex-2-en-1-one 

Relevant articles and documents

New DNA binding ligands as a model of chromomycin A3

Small molecules with DNA-binding affinity within the minor groove have become of great interest. In this study, new DNA-binding ligands were designed to mimic Chromomycin A3 (CRA3), which contains a hydroxylated tetrahydroanthracene

Enantiodivergent syntheses of (R)- and (S)- 3,5-dimethylcyclohex-2-en-1- ones from (R)-pulegone

R-(+)-pulegone (1) is transformed to (R)-5-methyl-2- (phenylsulfinyl)cyclohexanone (5) (65%, 3 steps). Sulfoxide 5 is converted to R-(-)-3,5-dimethylcyclohex-2-en-1-one (4) (53%, 4 steps) and S-(+)-4 (26%, 3 steps).