157667-92-0

Upstream product

• 53215-95-5 N-(trimethylsilylmethyl)benzylamine 
• 157668-05-8 (1-bromo-pent-4-enyl)-benzene 
• 102632-99-5 1-phenyl-4-penten-1-ol 
• 100-46-9 benzylamine 
• 100-52-7 benzaldehyde 

Relevant academic research and scientific papers

Photoinduced electron transfer (PET) promoted cyclisations of 1-[N-alkyl-N-(trimethylsilyl)methyl]amines tethered to proximate olefin: Mechanistic and synthetic perspectives

Upon PET reaction, amines of type 1 undergo efficient cyclisations to produce pyrrolidines and piperidines. Mechanistically, involvement of delocalised α-silylmethyl amine radical cation as reactive intermediate in such cyclisations are described.