15772-64-2Relevant academic research and scientific papers
Arsenous chloride-free synthesis of cyclic tertiary organoarsines from arylarsine oxides and di-Grignard reagents
Gregson, Aaron M.,Wales, Steven M.,Bailey, Stephen J.,Keller, Paul A.
, p. 77 - 83 (2015)
Abstract The growing importance of triarylarsines as ligands for transition metal catalysis has sparked recent interest in new synthetic routes to tertiary arsines that avoid hazardous arsenous chloride reagents. However, safer methods for the synthesis o
Systematic Study on the Catalytic Arsa-Wittig Reaction
Inaba, Ryoto,Kawashima, Ikuo,Fujii, Toshiki,Yumura, Takashi,Imoto, Hiroaki,Naka, Kensuke
, p. 13400 - 13407 (2020/09/21)
Efficient catalytic arsa-Wittig reactions have been developed by using 1-phenylarsolane as a catalyst. A wide array of aldehydes was converted to the corresponding olefins in high yields with moderate to excellent E stereoselectivity in the presence of a catalytic amount of 1-phenylarsolane. Moreover, density functional theory calculations were carried out to afford insight into the E/Z selectivity.
