27264-27-3Relevant academic research and scientific papers
Systematic Study on the Catalytic Arsa-Wittig Reaction
Inaba, Ryoto,Kawashima, Ikuo,Fujii, Toshiki,Yumura, Takashi,Imoto, Hiroaki,Naka, Kensuke
, p. 13400 - 13407 (2020/09/21)
Efficient catalytic arsa-Wittig reactions have been developed by using 1-phenylarsolane as a catalyst. A wide array of aldehydes was converted to the corresponding olefins in high yields with moderate to excellent E stereoselectivity in the presence of a catalytic amount of 1-phenylarsolane. Moreover, density functional theory calculations were carried out to afford insight into the E/Z selectivity.
Arsenous chloride-free synthesis of cyclic tertiary organoarsines from arylarsine oxides and di-Grignard reagents
Gregson, Aaron M.,Wales, Steven M.,Bailey, Stephen J.,Keller, Paul A.
, p. 77 - 83 (2015/03/30)
Abstract The growing importance of triarylarsines as ligands for transition metal catalysis has sparked recent interest in new synthetic routes to tertiary arsines that avoid hazardous arsenous chloride reagents. However, safer methods for the synthesis o
Some chemistry of organoarsenic and -antimony compounds
Jain, Vimal K.
, p. 224 - 229 (2007/10/03)
The interest in organoarsenic and -antimony compounds is being renewed due to their wide ranging applications which include as precursors for chemical vapor deposition of Group III-V semiconductors, versatile ligands and reagents in organic synthesis. The
